Reaction: Peroxynitrite can oxidise BH4 to the BH3 radical

- in pathway: Tetrahydrobiopterin (BH4) synthesis, recycling, salvage and regulation
Peroxynitrite can oxidise BH4 to the BH3 radical, further reducing BH4 availability to couple eNOS activity and compounding the production of superoxide through uncoupled eNOS activity (Kuzkaya et al. 2003).
Reaction - small molecule participants:
BH3. [cytosol]
BH4 [cytosol]
Peroxynitrite [cytosol]
Reactome.org reaction link: R-HSA-1497866

======

Reaction input - small molecules:
5,6,7,8-tetrahydrobiopterin
ChEBI:15372
peroxynitrite
ChEBI:25941
Reaction output - small molecules:
5,6,7,8-tetrahydrobiopterin radical cation
ChEBI:62772
Reactome.org link: R-HSA-1497866