Molecule: (4Z,7Z,10Z,13Z,15E,17S,19Z)-17-hydroperoxydocosahexaenoic acid

A docosanoid that is (4Z,7Z,10Z,13Z,15E,19Z)-docosahexaenoic acid carrying a hydroperoxy substituent at position 17S.
Synonyms for (4Z,7Z,10Z,13Z,15E,17S,19Z)-17-hydroperoxydocosahexaenoic acid :
(17S)-HPDHA
(17S)-HPDoHE
(17S)-hydroperoxy-(4Z,7Z,10Z,13Z,15E,19Z)-docosahexaenoic acid
(4Z,7Z,10Z,13Z,15E,17S,19Z)-hydroperoxydocosahexaenoic acid
17(S)-Hp-DHA
17S-HpDHA
17S-hydroperoxy-4Z,7Z,10Z,13Z,15E,19Z-docosahexaenoic acid
Molecular Formula: C22H32O4
Molecular wt: 360.488 g/mole
Charge: 0
SMILES: OC(CC/C=C\C/C=C\C/C=C\C/C=C\C=C\[C@H](C/C=C\CC)OO)=O
InChIKey: BNHQALRBDJVUQB-YTQNUIGOSA-N
InChI=1S/C22H32O4/c1-2-3-15-18-21(26-25)19-16-13-11-9-7-5-4-6-8-10-12-14-17-20-22(23)24/h3,5-8,11-16,19,21,25H,2,4,9-10,17-18,20H2,1H3,(H,23,24)/b7-5-,8-6-,13-11-,14-12-,15-3-,19-16+/t21-/m0/s1
CHEBI:136113
Sample reactions for this molecule:
GPX4-2 reduces 17(S)-Hp-DHA to 17(S)-HDHA
ALOX15 oxidises DHA to 17(S)-Hp-DHA
ALOX15 oxidises 17(S)-Hp-DHA to PDX
ALOX15 dehydrogenates 17(S)-Hp-DHA to 16S,17S-epoxy-DHA
Lipoxygenase oxidises 17(S)-Hp-DHA to 7(S),17(S)-diHp-DHA