Molecule: (7Z,10Z,13Z,15E,17S,19Z)-17-hydroperoxydocosapentaenoic acid

A (7Z,10Z,13Z,15E,19Z)-17-hydroperoxydocosapentaenoic acid in which the chiral centre at position 17 has S-configuration. An intermediate of specialised proresolving mediators.
Synonyms for (7Z,10Z,13Z,15E,17S,19Z)-17-hydroperoxydocosapentaenoic acid :
17(S)-Hp-DPA(n-3)
17(S)-HpDoPE(n-3)
17(S)-hydroperoxy-omega-3-docosapentaenoic acid
Molecular Formula: C22H34O4
Molecular wt: 362.504 g/mole
Charge: 0
SMILES: OC(CCCCC/C=C\C/C=C\C/C=C\C=C\[C@H](C/C=C\CC)OO)=O
InChIKey: PQYYUXHETXYOCV-DKMPAXASSA-N
InChI=1S/C22H34O4/c1-2-3-15-18-21(26-25)19-16-13-11-9-7-5-4-6-8-10-12-14-17-20-22(23)24/h3,5-8,11,13,15-16,19,21,25H,2,4,9-10,12,14,17-18,20H2,1H3,(H,23,24)/b7-5-,8-6-,13-11-,15-3-,19-16+/t21-/m0/s1
CHEBI:140226
Sample reactions for this molecule:
ALOX5 oxidises 17(S)-Hp-DPAn-3 to 7,17-diHp-DPAn-3
ALOX5 dehydrogenates 17(S)-Hp-DPAn-3 to 16(S),17(S)-epoxy-DPAn-3
ALOX15 oxidises DPAn-3 to 17(S)-Hp-DPAn-3